SYLLABUS

Course: CH 331 Physical Chemistry I
Semester: Fall, 2023                                                                                                                                                modified August 23, 2023

Professor: Carl Salter
Collier 221         Phone: 610-625-7920    email:  salterc at moravian . eduCATION

Required Text:   Physical Chemistry: A Guided Inquiry: Thermodynamics J. N. Spencer et al.

Additional Texts: P. W. Atkins, Physical Chemistry, 6th Ed. Freeman, 1998                            
                            Rodney J. Sime, Physical Chemistry: Methods, Techniques, and Experiments Saunders College Publishing, 1990
                                        (Both textbook are available in the Superlab Commons.)

Additional online resources:
P chem textbook
https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps
contents
https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Map%3A_Physical_Chemistry_for_the_Biosciences_(Chang)/00%3A_Front_Matter/03%3A_Table_of_Contents

Table of integrals https://biomachina.org/courses/structures/supporting/integral_tables/integral.htm
Energy converter
http://www.colby.edu/chemistry/PChem/Hartree.html
Vensim simulation software https://vensim.com/free-download/
Basic program compiler https://www.jdoodle.com/execute-freebasic-online/
Moravian WebMO http://pauling.cs.moravian.edu/~chem/cgi-bin/webmo/login.cgi

HCl table of conc properties
AcOH table of conc properties

It is crucial that you keep up with assignments. If you have struggled with a problem and no solution is in sight, please call me or come by my office. It is much easier for both of us if you deal with these problems immediately. When I took physical chemistry, I saw my professor about twice each day. There is simply too much information to absorb by yourself; you need to "talk out" these new ideas with someone: if not me, then a classmate.

Homework sets including computer projects will be due at the end of each week. See the schedule of topics for assigned problems. You should attempt all the exercises at the end of each chapter because they closely follow the presentation of the text, and therefore aid comprehension of the material. 
No homework may be submitted after 5 pm, Friday Dec 8, the last day of class.

Two short reaction essays are also included in your homework grade: 
DUE Friday Oct 6.
Phillip Morrison Ring of Truth,  Episode 2  "Change". I also have this on DVD.  Just the second half of the episode on energy (at time 21:00 - it starts when you see bicycles!)

DUE Monday Nov 20. 
G.F. Martins,
Why the Daniell Cell Works, Journal of Chemical Education 1990, 67 (6), p 482.  (If you're a Chemistry major)
OR
S. O. Russo and G. I. H. Hanania Ferrimyoglobin-fluoride: An undergraduate kinetics experiment J. Chem. Educ., 1990, 67 (4), p 352
. (If you're a Biochemistry Major.)

Policy on the use of AI: AI tools can assist you in providing explanations and suggestions, but they should not be used for direct answers to graded assignments, quizzes, or examinations. Students should not submit AI-generated content as their own work; this will be viewed as a form of cheating or plagiarism. Be wary of AI-generated content – the information provided by AI can be inaccurate or incomplete. Students are encouraged to meet with the course instructor, PASS leader, or peer tutors for clarification on course content.  

Lab reports are an important part of this course.  Lab reports for each lab experiment will be due one week after the completion the experiment. You must turn in all lab reports to receive a passing grade in the course.  Unacceptable lab reports will not be accepted!  You will be required to resubmit an unacceptable lab report.  You are required to work with your lab partner--the two of you must read and evaluate lab reports before they are turned in to me.  An extensive list of online advice about lab report format, style, and content is available on my web site.  The lab report evaluation form is also on my web site.  During the semester there will be lab report writing workshops during lecture--it is crucial that you bring writing assignments to class on those days. 
No resubmitted lab reports will be accepted after 5 pm, Tuesday Dec 13, the day after the final exam.

Attendance:    After two unexcused absences you will receive written notice that a third unexcused absence will result in failure of the course.  Students are required to complete missed material immediately after their return from any absence.  For planned absences such as travel for a college event, students are expected to complete missed material before the absence occurs.

Laboratory: The laboratory course gives you the opportunity to measure physical and chemical constants. I will emphasize the importance of statistics in determining how precisely you have measured these constants. In fact, the early experiments are designed to teach you the use of statistics in evaluating experimental data.

Class                   Heat of Fusion of Ice
                           How much air? Propagation of Error
                            Gas Constant by Electrolysis of Water
                            Identification of a "Broken Label" sample

Pairs                    Freezing Point Depression of Water by Acid
                            Partition Coefficients (log P) of Methylene Blue and Brooker's Merocyanine 

                            Partitioning Acid-Base Indicators  

                            Enthalpy of Solution (solution calorimetry)                                                  
                            Vapor Pressure (critical state apparatus)
                                                       
                            pKa of a acid-base indicator (visible spectroscopy)
                            Effect of Ionic Strength on Acetate Buffers 

                            Gas thermometry: Determination of Absolute Zero
                            Heat Capacity Ratio of Gases
                            Refractive Index using Lasers
The lab instructor will determine the groups and partners for all lab experiments.

You will find that I do not provide detailed lab handouts that tell you exactly how to do an experiment. In the lab you will find general information about the goal of the experiment, but it is up to you to decide how to do your experiment. And it is your experiment; you should have the pleasure of deciding how you want to do it. If I tell you how to do the experiment, you won't have as much fun because you'll be trying to get results that please me. All I care about is that you design an experiment that really measures what you want to measure, and that you estimate the precision of your measurement. Of course, I'll be there whenever you want to talk to me about your experiment. And in that regard, let me warn you that I am very opinionated and hold very definite ideas about the way things should be done in the lab. This is an inevitable consequence of spending twenty five years of my life doing chemical research. My job is to use my experience to help you avoid bad ideas and mistakes. Nevertheless, if you believe an idea you have is right, don't drop it just because I say it's wrong. Stick with it until you understand why it is wrong, or until you can prove to me that it is right.

You should keep some organized record of the work you do in lab, but I want you to decide how you want to do that; I am not going to grade your personal notebook. I will from time to time call you into my office and ask you to answer questions about your lab work; you can bring in your notebook and refer to it during these interviews. Therefore you need to record information in your notebook so that several weeks later you will be able to look at it and know what you did in the lab. By the way, you do not need to write down a detailed experimental procedure in the notebook; instead, refer to the lab textbook where you found the procedure. If you modify the procedure or apparatus, be sure to record the modifications in your notebook and lab report.

IGNORE material stored below
Groups will be rotated every two weeks on Monday.  On the Monday before the new groups are assembled, there will be an in-class quiz with one problem based on homework.  If every member of the group gets the problem right, one additional bonus point will be added to the previous week's quiz for every member of the group.

Class                   How much air? Propagation of Error
                            Heat of Fusion of Ice
Class                    Freezing Point Depression of Water by NaCl (temperature, conductivity)
                             Partition Coefficient of Acetic Acid                                                                

Pairs                     Enthalpy of Neutralization (solution calorimetry)
                             Bomb calorimetry                            
                             Real Gas Behavior (critical state apparatus)
                            Gas Constant by Electrolysis
                            pKa of a acid-base indicator (visible spectroscopy)
                            Effect of Ionic Strength on Acetate Buffers 

                            Gas thermometry: Determination of Absolute Zero
                            Heat Capacity Ratio of Gases
                            Refractive Index using Lasers
You may work in the lab at night, but you must not work alone!  The person in the lab with you does not have to be a member of the physical chemistry class.


The sad case of Dr. Isaiah Norman http://www.220.ro/desene-animate/Jonny-Quest-The-Invisible-Monster-1/wlsSrE6Cib/